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How To Prepare For The Holiday Season— And Enjoy It!

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How To Prepare For The Holiday Season— And Enjoy It!
Do you feel a tinge of envy when someone proudly tells you they’ve gotten their Christmas shopping completely done— in September? Well, you know the old saying: If you can’t beat them, join them.There’s still time to get an early jump on things to ensure that you have a successful, less stressful holiday season. A little foresight, planning and organization are all you need. 
Facebook Live: Soaping in Slippers Facial Cleansers

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Facebook Live: Soaping in Slippers Facial Cleansers
Soaping in Slippers is back! For this episode, we make handmade Micellar Water, Facial Cleansing Oil, and a foaming Grapefruit Face Soap. Join Debbie as she makes all three facial cleansers with Abby from the Wholesale Supplies Plus Marketing Department.
Properties of Oils

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Properties of Oils
Whether you’re handcrafting soap for a business or tackling a new weekend DIY hobby, choosing the best oils for soap making is part of the fun. Speciality oils offer emollient properties as well as other benefits for the skin and hair.
How Do You Stand Out From Your Competition

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How Do You Stand Out From Your Competition
Setting yourself apart from the competition doesn’t require a significant investment, change in strategy, or earth-shattering product idea.  In fact, you’re already armed with most of the tools you need to start creating a brand identity that customers will notice, and remember. Here are few simple ways you can stand out from your competition.
Liquid Soap Recipe from Scratch

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Liquid Soap Recipe from Scratch
Learn how to make liquid soap from scratch with this guide by Wholesale Supplies Plus! Making liquid soap from scratch is easier than ever with our recipe.
Troubleshooting: Making Lotion From Scratch

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Troubleshooting: Making Lotion From Scratch
1. Challenge: The water and oils separate.Lotion is made up of waters and oils. The two naturally want to separate so an emulsifying wax is used in the formulation to help them stay together. If not enough emulsifying wax is used or if water is added to a really thick lotion the marriage breaks up and the oil will float on top of the water....
Beeswax Recipes! How to Make Wickless Candles

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Beeswax Recipes! How to Make Wickless Candles
This week we highlight beeswax. We have four new recipes that use beeswax and in this video we will show you how to make one of the recipes. A wickless candle throws beautiful aromas in your home without the open flame. Learn how to make them in this video.
How You Can Actually Take Time Off For Spring Break

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How You Can Actually Take Time Off For Spring Break
Many small business owners enjoy their work, however, how much is too much? With a little bit of planning you can step away for a much needed break!
The Chemistry behind Alcohol and MP Soap

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The Chemistry behind Alcohol and MP Soap
Because the chemistry of Cold Process (CP) soap is delightfully complex, I have spent many happy hours devising experiments to answer questions and solve problems for those who make CP soap. Makers of Melt and Pour (MP) soap, however, face problems different from those I have investigated before. For example, while CP and MP soaps can be poured in layers, CP layers are usually at the same temperature and in the same state (liquid). But a hot, liquid MP layer is usually poured on top of a cold, solid MP layer, and because of these differences, the joint between layers may not be strong. Additionally, transparent soap is much more common in the MP world than it is in the CP one, and so bubbles and blemishes within a transparent layer must be minimized. Fortunately, makers of MP soap have largely solved both of these problems by spritzing each layer of soap with alcohol. So all that remains for me is to figure out why this works. To begin with, I have to distinguish two usages for the word soap. For chemical and regulatory purposes, soap is an alkali salt of a fatty acid. But MP “soap” is almost always a blend of soaps, solvents, and detergents. For this project I used Crafter's Choice Premium Extra Clear Soap, which consists of sorbitol and propylene glycol (solvents), sodium laureth sulfate (detergent), sodium stearate and sodium myristate (soaps), and sodium cocoyl isethionate (detergent). Crafter's Choice Premium Ultra White Soap has the same ingredients plus titanium dioxide colorant.I also need to clarify the word alcohol. This is actually a family of chemicals with some familiar members. Ethanol (ethyl alcohol, grain alcohol, Everclear) is the one used in beverages. Isopropanol (isopropyl alcohol, rubbing alcohol) is the one used for first aid. Soaps and detergents are surface-active agents, or surfactants, meaning that they form organized structures at aqueous surfaces. The molecules organize into a film on top, which we recognize as bubbles, and into droplets called micelles in the interior. When soap or detergent is added to water, they don't actually dissolve—they form an emulsion. You can see this for yourself by adding, for example, one gram of MP soap to 200 mL of hot water. A soap/water emulsion is cloudy (because of the micelles), not transparent, with bubbles at the surface. In contrast, soaps and detergents actually dissolve in ethanol and isopropanol. Rather than forming a cloudy emulsion with bubbles at the surface, a soap/alcohol solution is transparent, with no bubbles. The soap and detergent molecules do not organize into films and micelles, but float around in the alcohol as individual molecules. Figure 1 shows a soap/water emulsion on the left, and soap/ethanol and soap/isopropanol solutions in the center and on the right. Even when these solutions are shaken, no bubbles form because the soap molecules do not form a film at the surface. So when you spritz alcohol onto bubbles at the surface of MP soap, the soap dissolves in the alcohol. The ordered film of soap molecules breaks up into individual molecules, and the bubbles disappear.In addition to removing bubbles, I wanted to explore whether alcohol helps soap layers to adhere to one another. I began by supposing that alcohol dissolved some of the soap at the surface of a cold, solid layer of soap, and that when hot liquid soap was poured on top of it, the hot liquid mixed with the soap solution, forming a zone containing soap from both layers. But how to test this hypothesis? I wanted to pour two layers that could be easily distinguished from one another, so I chose a transparent layer and a white layer. I also wanted to be able to try to break the layers apart so that I could see whether they had, in fact, blended together. But layers are most frequently poured horizontally, and pulling apart such layers seemed problematic at best. So I opted to pour two white bars of soap. After they cooled to room temperature, I cut each bar in half and returned a white half-bar to the left side of four single-bar molds. I then poured transparent soap into the right side of each mold. The result was four bars, each with a white half and a transparent half, as shown in Figure 2. I wanted to be able to treat the white/transparent interface of each bar to see what, if any, effect alcohol might have. One bar was not treated. The interfaces of the second, third, and fourth bars was treated with water, ethanol, and isopropanol, respectively. The joint between the layers was crisp and clean for three of the bars, but the one treated with water had visible tendrils of white soap penetrating the transparent layer. I then tested each joint by laying it over a pencil and pressing the ends down with both hands, as shown in Figure 3. The untreated bar broke cleanly at the joint, with no white soap clinging to the transparent soap. The bar treated with water did not break over the pencil; it just bent. I had to use all my strength to break it with my fingers and thumbs, and when I did, there was lots of white soap adhering to the transparent soap. The bar treated with ethanol broke with some difficulty over the pencil, and there was some white soap adhering to the transparent soap. Finally, the bar treated with isopropanol broke cleanly over the pencil, with no white soap adhering to the transparent soap. Figure 4 shows the broken joints, face up. Compared to the untreated bar, the one treated with water had the strongest joint, but streamers of white soap visibly penetrated the transparent soap. This could be an interesting feature if done on purpose, but most people would consider this a blemish. The bar treated with isopropanol was very similar to the untreated bar. In a horizontal layer, bubbles could weaken the joint, and spraying with isopropanol may eliminate bubbles, but it does not seem to otherwise improve the joint. The winner in this round was ethanol. The white/transparent interface remained crisp and clean, but the joint was noticeably strengthened compared to the untreated bar.This does not mean you have to ditch isopropanol for ethanol. After all, if it ain't broke... But if you have a problem with weak joints between soap layers, ethanol may provide improved adhesion between layers without sacrificing clean lines. And if you want some interesting texture, you may want to investigate a joint venture with water.
Time and Temperature

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Time and Temperature
Taking a look at temperature profiles for cold and hot process soap. Last month we looked at the possibility of using very high temperatures to shorten the time needed to completely saponify an oil. In extreme cases, this may happen in as little as 5 minutes. One might assume that “hot process” (HP) and “cold process” (CP) soaps differ in the temperatues used, but the designations have more to do with technique than temperature. In the hot process, oils and lye are mixed in a container capable of applying heat to the mixture. The source of heat might be a crock pot, microwave oven, conventional oven, or hotplate. The soap batter is typically heated until it reaches gel phase and the saponification reaction is complete. Interestingly, it is possible to make HP soap at low temperature by using only gentle heat. In the cold process, oils and lye may be heated, but no external heat is applied after they are mixed. The bulk of the saponification reaction happens in the mold. Also interestingly, it is possible to make a CP soap at high temperature just by heating the oil, as described last month. Here we will explore the relationship between time and temperature. Typically when lye is mixed with oil, the mixture becomes gradually more viscous until it reaches trace. The batter then continues to thicken until it no longer flows. At this point it is essentially a solid. But if conditions are right, the solid soap remelts, a condition called “gel phase” by handcrafted soapmakers, and “neat soap” by commodity soap chemists. The temperature at which this phase transition happens depends on the oils used and the lye concentration.Consider, for example, our standard four-oil blend: coconut oil 28%, palm oil 28%, olive oil 39%, castor oil 5%. We can make soap from this oil using lye with a wide range of concentrations. A medium-water soap, typical of what many people use, might use lye with a concentration of 33% NaOH. A low-water soap, (often referred to as a “water discount”) might use lye with a concentration of 40% NaOH. The temperature profiles of these soaps depend on the starting temperature when the oils are mixed with the lye. A temperature profile is a useful way to characterize a soap formula. Simply heat the oil to the starting temperature you wish to explore and, after mixing with your lye, measure the temperature periodically over the course of a couple of hours. An infrared thermometer is particularly convenient for this task, since you just point and click to take a reading. A stopwatch (perhaps on your smartphone) is convenient for measuring time.You don't have to hit an exact starting temperature, and the lye need not be at the same temperature as the oil. For example, you might intend to start at 100°F, but because your lye is at room temperature, you could wind up at 95°F after mixing. Just record the actual time and temperature. You will want to record the temperature frequently (about once per minute) at the beginning when the temperature is changing rapidly. You can then record less frequently as the soap slowly cools. It is not important to hit any particular time or temperature. Just record the actual time and temperature as close to one another as possible. If you notice the soap moving into gel phase, be sure to make a note of it. Figure 1 shows a temperature profile for a medium-water soap. The horizontal line at 71°C (160°F) marks the division between gel phase and solid soap. The soaps labeled 40°C and 60°C never get warm enough to reach gel phase. They gradually warm as the exothermic saponification reaction proceeds. Eventually, the heat produced by the reaction is less than that lost to the surroundings, and the soaps slowly cool. The soap labeled 65°C gradually warms until it reaches gel phase. Then the reaction takes off, climbing well above the gel temperature. The two hot soaps start above the gel temperature and the saponification reaction proceeds very rapidly. They hit peak temperatures in a matter of minutes, and once saponification is complete, they cool more rapidly than the other soaps because no further heat is coming from the reaction. Figure 2 shows a temperature profile for a low-water (water discounted) soap. With a lye concentration of 40%, this soap gels at 87°C (189°F), much higher than the medium-water soap does. While the soaps labeled 40°C, 60°C, and 65°C get hotter than the corresponding medium-water soaps, they do not reach this higher gel temperature. Only the two hottest soaps reach gel phase, and they do so very quickly. The specific temperature for the gel phase transition depends on the oils used as well as the lye concentration, but the general trend is that the gel temperature increases as the lye concentration increases. At the same time, soaps made with high-concentration lye get hotter than those with low-concentration lye, and they do so more quickly. Whether or not a soap gels depends on whether the soap reaches the gel temperature. The temperature profile also gives you a clue as to how quickly the saponificiation reaction is completed. When the temperature reaches its peak and begins to decline, it is because heat is being lost to the surroundings more rapidly than it is being produced by the reaction. The temperature profile can also be used to diagnose problems with ingredients that are adversely affected by high temperatures. While measuring the profile on a batch, notice the temperature at which the adverse effect takes place. In subsequent batches, you can gradually decrease the starting temperature or decrease the lye concentration to prevent the soap from getting too hot.The temperature profile is very easy to add to a batch record. It requires only a thermometer, a stopwatch, and a few extra minutes to write down the time and temperature. You can plot the data on graph paper or using a spreadsheet, or you can just look at the data without plotting it. While you may not bother to record it for every batch, it can be useful for diagnosing problems and solving them. Footnote:1. Data in this article were collected by students John Campbell, Andrew Basinger, Tyler Bowman, and Ron Davis under the supervision of Kevin Dunn. Parts of it are documented in Chapter 22 of Scientific Soapmaking (Kevin Dunn, Clavicula Press, 2010).
If the World Hands You Lemons

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If the World Hands You Lemons
Following this month's citrus theme, I thought I would explore the properties of two compounds common to all citrus plants: citric acid and limonene. Though they come from the same fruits, these two chemicals could not be more different from one another. One is soluble in water, the other isn't. One has a strong taste, the other a strong aroma. One will sequester metal ions, the other will dissolve grease and many adhesives. Two powerful and commercially important chemicals from the same little package of lemony goodness. Before we discuss these molecules, we need to review a little water chemistry. You probably don't even remember when you learned the formula, H2O. It is simply common knowledge. But those three little atoms dominate the properties of the world as we know it. Hydrogen and oxygen atoms are bound to one another by electrons, which carry a negative charge. But they don't share those electrons equally. Oxygen is a relative electron hog, and hydrogen is a light-weight. The result is that oxygen atoms in water are partially negative, and hydrogen atoms partially positive. Opposites attract. The negative oxygen atom of one water molecule is attracted to the positive hydrogen atoms of each neighboring water molecule, and vice versa. The result is that water molecules are attracted to one another more strongly than they are to just about any other molecule. Figure 1 shows a structural formula for citric acid. As discussed in last month's column, a structural formula is the kind of thing that a chemist can easily draw on a napkin when talking to another chemist. A structural formula tries to include the most important details about the molecule without worrying about extraneous details. Each line represents a bond, and if two bonds join with no explicit atoms, the bonds are assumed to join two carbon atoms. Each carbon atom bristles with one, two, or three hydrogen atoms, but the structural formula leaves them to your imagination. Though all organic molecules contain carbon, their chemical properties are dominated by the atoms other than carbon.This formula has seven oxygen atoms, four of which are bound to hydrogen atoms. The other three oxygen atoms are “double bonded” to carbon atoms. That grouping of a double bonded oxygen next to an OH is instantly recognizable to a chemist as an acid group, and if it looks familiar, you may be remembering it from last month's column. It is the same grouping at the hydrophilic head of a fatty acid. Citric acid has three such groups, which packs an awful lot of acidity into a tiny, little package. To a water molecule, those OH groups are nearly as attractive as other water molecules. For this reason, citric acid is quite soluble in water (and saliva). And because three of those OH groups are next to double-bonded oxygen atoms, the hydrogen atoms are acidic. The defining property that led chemists to recognize acids as a group is that they taste sour. And citrus juices contain both citric acid and various sugars, leading to the combination of sweet and sour we describe as “tangy.”Citric acid has one more property that makes it important for makers of soap and cosmetics—it can bind to metal ions in aqueous solution. Metal ions like calcium or iron can have deleterious effects on soaps and cosmetics. Calcium from hard water, for example, combines with soap to produce soap scum. In a high-pH product like soap, sodium citrate (the sodium salt of citric acid) can be used to tie up these metals, preventing them from binding to soap. Citric acid isn't the only useful chemical to come out of citrus fruits. Figure 2 shows a structural formula for limonene. While it's squiggly lines show how the carbon atoms are linked together, perhaps the most important thing about it is what you don't see. No oxygen. If you were a water molecule looking at limonene, you would find no familiar OH groups. A molecule like this is not soluble in water (or saliva), and consequently has little or no taste. And where do you find limonene? Not in the juice of the lemon, but in the oily rind. Limonene is a principle component of the oils pressed from the rinds of all citrus fruits.Not only is limonene not attractive to water, the absence of atoms other than carbon and hydrogen means that it isn't strongly attracted to other molecules generally. That means it can easily evaporate, traveling from the rind, through the air, to your nose. That's why you can smell limonene in citrus oil, but not citric acid in the juice. Finally, because it does not dissolve in water, limonene is good at dissolving other things that are insoluble in water, things like adhesives, tar, and grease. That's why citrus oils have become useful as alternatives to petroleum solvents. The detailed chemistry of these two molecules is beyond the scope of this article. But you are now able to look at structural formulas on websites and instantly know something about why a molecule behaves as it does. If it has an OH group, it interacts strongly with water. If it has multiple OH groups, it likely is soluble in water and saliva, has a strong taste, and not much of an aroma. If a molecule has no OH groups, it is likely insoluble in water or saliva, and relatively flavorless. I don't know about you, but after all this talk of molecules, I have a hankering for some lemonade.
Self Love

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Self Love
As Valentine's Day approaches, who are the people in your life who you think most about? Is it a significant other or your children? How about yourself? It's ok sometimes to show yourself some love. Here are some of the most common behaviors of people who are not practicing self-love. Ah, it’s February. Hearts, flowers, and sentiments of love are in the air! It’s a wonderful time to pause and contemplate those who are near and dear to your heart and all they bring into your life.Who is the first person you think of as Valentine’s Day approaches? Your mate and children are possibly the most likely recipients for those little boxes of chocolate goodies and cute cards bearing sweet words of love and appreciation. But let me ask you this: when was the last time you did something really, really nice for yourself?The calendar is filled with constant reminders to show appreciation to the important people in our lives, but there isn’t a single day on the calendar that reminds us to turn our love and appreciation inward. Where is National Self- Love Day anyway? I think it would do us good to celebrate ourselves for a change, don’t you?Some people believe that taking care of and treating themselves with the same kindness and generosity that they treat others is self-indulgent. Some simply don’t want to take the time learn new habits and place attention on their own needs and desires. In my experience as a coach, these folks are typically overworked, unhappy, and exhausted. Many of them are nowhere near the level of success that they wish to achieve and some are even suffering miserably. All because the love that they hold in their hearts is rarely directed inwardly.But this can change with a shift in mindset and a newfound appreciation of your special qualities, gifts, and spirit. I’ve seen people turn their lives and businesses around simply by raising their self-awareness and acting on the desires that they previously deemed as selfish and indulgent. I can promise that as you grow to appreciate and honor yourself, it will be reflected in the world around you: in your business, relationships, and even in your finances. So what are the signs that you’re not showing yourself enough love and appreciation? Here are some of the mostcommon behaviors that I witness in someone who lacks self love. I’ve also included some mindset tips on how to turn that behavior around. I suggest journaling about the steps you take, how it feels, and what you notice as time goes by. The act of journaling will raise your awareness and help you to see where you need to improve and how far you’ve come. Journaling is yet another act of self love! Negative Self-Talk When you make a mistake, get clumsy, or say something that you regret how do you react? Do you call yourself names, throw fits of anger, blame others? This is one sure sign of selfloathing rather than self-love.Instead: Simply observe; as though you are 5000 feet above the situation. Oftentimes we respond negatively because we are overwhelmed and preoccupied. If you begin to lose patience with yourself take a deep breath and think about how you would treat someone you love when they make the same mistake. Can you treat yourself in the same way? With practice you can. Staying Too Busy When I have a coaching client who cites a lack of time for their inability to rest and play I can usually prove them wrong. People who don’t appreciate themselves often feel guilty for taking time to self-nurture, relax, and play. They unconsciously busy themselves with menial tasks instead. Do you really need to refill the paperclips and go over that expense report for the third time today?Instead: Be honest with yourself about how you’re spending your time and what you may be avoiding. Then make a list of things you would like to do once you give yourself permission to pay attention to your own needs and desires. If you have a go to list you won’t have to give it any thought and may not talk yourself out of something that puts you in the spotlight. Indulge a little, you might just get used to it! Putting Everyone Else First The airlines say it the best: “Please apply your own air mask before assisting young children and those around you.” In other words, what good are you to others if you’re dead? Taking care of yourself is yet another expression of love. When you care enough about yourself it tells those around you that you love them enough to stick around. This is not a selfish act! Ironically, most people who bow to the needs of othersdo it to satisfy their own needs, not those of everyone else. If you were to ask your spouse, parent, friend, and maybe even your children what their expectations of you are, I’m certain that their thoughts would differ from yours quite a bit.Instead: You’ve made a list of things that are important to you; activities that you can do just for yourself. Now determine your non-negotiables: things like exercise, proper nutrition, alone time, a monthly massage, a night out with the girls or guys. Now schedule those things on your calendar. These are dates with yourself that can no sooner be cancelled than an important client meeting. As you become healthier, more balanced, and acknowledge your own deserving those around you will appreciate you all the more!